Just wanted to address this. I don't think any of us at this point know what the full intention was, but FlightAware showed no history on that tail number meaning it hadn't flown in several months. The annual inspection apparently did include some level of paint and the control surfaces removed. It was probably significant in terms of what was touched all around.
But, this wasn't just a Navajo, this was a P-Navajo (PA-31P-425). Navajos are thirsty, the TIGO-541s in P-Navajos are moreso. I'm not sure normal expected fuel burn numbers, but takeoff as I recall is north of 50 GPH per side.
Point being, yes it seems it was a bit on the high side. But with reserves that could be a couple hours, and he may have wanted that for some of his post-MX checks of all systems depending on what else was done (maybe including making sure the fuel gauges were working correctly, or maybe it was known they didn't - as is often the case on Navajos). I might've done similarly depending on what I was wanting to check and what maintenance had been performed.