21.93 not applicable in this scenario. A major/minor
change to type certificate is not the same thing as a major/minor
alteration. Major/minor changes to TC are outside the ability of a A&P/IA and are determined at the FSDO/MIDO/FSDO levels. Plenty of guidance docs on this:
"The use of the terms “major” and “minor” are sometimes inappropriately applied or misunderstood. A major change in type design can be approved only by an ACO as an amended type certificate (ATC) or Supplemental Type Certificate (STC). A major alteration requires the use of FAA-approved technical data. Minor alterations only require data that is acceptable to the FAA. During an evaluation, an anticipated major alteration may be subsequently classified as a major change in type design, and thus would require application for an amended TC or STC."
https://www.faa.gov/documentLibrary/media/Order/8300_16_CHG_1.pdf
In your battery example, if the replacement battery is of the same type (25, 35) and weighs the same within a pound you can swap it out as a minor alteration per the above mentioned AC23-27. Unfortunately, the weights are different so the AC would not apply so that would take you back 43 Appx A(a)(vii). However, if your replacement battery is PMA'd as a
replacement (plug n play) for your aircraft model then it could also be installed under a logbook entry and an A&P correction of the wt/bal report. Anything short of that would fall under a major alteration.
Where 21.93 (major change) could come into play is if this 12v dry cell has no approval and you apply for a field approval to install. If the FSDO determines it is not a minor change to TC then they would forward your request to the ACO. If the ACO determines it's a major change to TC then you would have to pursue a STC to install it and not a field approval.