If it's your first long trip with the family, plan to get to ATL area EARLY in the morn or LATE in the evening (dark+). Even if that means leaving DC before sunrise and having your pax sleep for the whole flight. It is HOT and humid here now and that does not equate to favorable flying conditions for new GA passengers. Depending on where in the ATL area you are going, you could be stuck under the Bravo shelf for quite a while. 20 minutes at 3,000' at 3pm instead of 8am could be the difference in you having passengers for the return trip, or you going broke from buying last minute airline ticket(s) back to DC.
This time of year, you will usually notice a well-defined haze layer anywhere from 3,000' to 9,000' (you'll know it when you see it). Try to get above it if at all possible - your passengers will thank you for it. The last couple of trips I've made, I've gone up to 10,000' for a trip that only took 1:15 to complete to get above that haze 'cap' - the difference in flying (and riding) conditions is enough of a difference that I was willing to spend the fuel to get up that high.