I accept your challenge, sir!
The atmospheric pressure will be immense towards the center of the Earth. Even though the net gravitational attraction goes to zero at the center, you have the weight of a whole lot of atmosphere above you. It is also very hot, so I'd guess that the air will actually be in a very dense supercritical state where it is neither liquid nor gas. The result will be that your aerodynamic drag will be massive around the same time that your gravitational acceleration goes to zero.
So, even with a really big JATO pod, you're pretty much going to hit terminal velocity before you hit the center of the Earth. The JATO bottle will only effect the details of where you hit terminal velocity. Because the drag is so large, you won't overshoot the center by very much before you get pulled back down.
Therefore, you were obviously asking me a trick question. The answer is to wait until the instant you start to fall back towards the center of the Earth (your apogee), then let off the JATO bottle. Because of the massive drag down there, your most efficient strategy will be to move fairly slowly at first, letting off multiple bottles in series instead of just one bottle.
Did I pass?
Chris