I think what you should look at is the failures and capabilities of both systems.
Most aircraft only have one or the other, so that will box you in. Some Beech products have the option depending on which you buy. If you get a Cirrus, it'll have TKS. If you get a 310, it'll have boots. Personally, I would buy the plane I want first.
You mention FIKI. Do you mean true FIKI or a "full de-ice" setup? There's a difference first in purchase cost, sometimes in system complexity (and thus ownership cost when it breaks), etc. The 310 I fly is a non-FIKI bird. It is simple and has been cheap to keep working so far. The FIKI boot systems usually have extra boots, timers, etc. Yes, they are functionally better, but not by a ton and they can have all sorts of failures that are hard to diagnose. Also, FIKI isn't always better, just certified. For example, I think the alcohol windshields do a better job on 310s than the hot plate. But, for FIKI you need the hot plate.
Boots are nice because they don't have a bottle of fluid that runs out. That's about it, though. They work pretty well but require much closer monitoring as the FAA's "blow the boots immediately" is not a mantra I've heard a single experienced ice pilot agree with. So, 1/4" or so is usually what people want to wait for to get a clean break. Boots require getting some maintenance to keep them clean and shiny which helps shed ice. Power for boots comes from the outlet side of vacuum pumps, so you can't get rid of the pumps even if you go all glass. The valves can break, boots can leak, and you often won't notice it until the ice won't come off. I've had boots fail 2 or 3 times, electric prop de-ice fail more times than I can count - the wires are prone to getting frayed and broken from spinning around so fast, I had brushes go out, etc.
I've never flown with TKS, but turn it on and then monitor. I like that. I wouldn't ever sit around in icing with it, but I like the system design better.
I like the 310 and I think it's a great option for a de-iced plane. I wouldn't get a Baron instead because of TKS. But if I was going to buy a Baron, I'd look for one with TKS over boots.
If you have any questions on the various de-iced/FIKI twins out there I have experience with a lot of them.