Thanks for the information, I'm going to hunt down the voltage testing guide and bring it with me. I will be surprised if it is the battery but acknowledge it certainly could be. That's one thing that confuses me: the ammeter always showed a nominal charge, even last night. I check it every flight without fail. If the battery were failing, wouldn't the ammeter show a high charge rate after start?
I'll certainly post more after we find out what the problem is. The good news is we have A&Ps at the ready should we need to affect repairs in the field. We won't do anything unsafe or illegal.
No, as batteries fail they go through a process of sulfation, where the plates gradually degenerate, and don't have enough surface area to maintain a good charge. The charge rate will actually decrease as the battery ages because it can't take as large, or fast of a charge anymore. Without going into all the details, they just 'wear out', and the chemistry no longer changes it's ionic property.
Go by Oreilly's and get a hydrometer, sometimes called a battery chemical tester. It's a little glassine bulb with a rubber squeeze on the top, and a little dipper neck. Open all the vent caps on the battery, stick the dipper tip into the fluid, squeeze the rubber cap and release to pull the battery fluid up into the glass envelope. There are four little colored balls in the bulb that will give the condition of the battery chemistry by the specific gravity. Check it first thing before you start messing with the electrical stuff. If none of the balls float, the battery is toast. Put the fluid back into the cell and rinse it with some fresh water, then go on to the next cell.
Check the voltage at the battery terminals, and record the voltage. Then go through that Skytech guide. Go back and record the battery voltage again. Compare it to the first reading, it should be pretty close. If it's much lower the battery is in poor condition, but depending on the plates, and the electrolyte, it could possibly be recharged.
Your battery will not blow up as long as the voltage regulator terminals are not stuck closed. The regulator on a generator is one of those black boxes with three wires sticking out of it like you used to see on an old chevy on the fender. It will limit the battery voltage charge to the limit of the charge rate of the battery specifically so it won't overcharge and damage or destroy a battery. They are set at the factory, and are not adjustable. Stuck regulator contacts is very rare.
Once the engine is running, just monitor the ammeter for what looks like normal conditions you are used to. It may require some high charge rate for the first few minutes. If the charge rate pegs on the meter, and stays there, shut the engine off and investigate the regulator, or just disconnect the wires and tape them up until you get home. The generator will not be producing power, so you don't have any electrical to run your panel stuff, leave the master off unless you really need some comm, or txp, or whatever, but conserve battery until you absolutely need it, and then turn on just what you need to be safe(nav, comm, GPS). Be prepared to run out of battery power, and have a backup plan.