The Wx500 in my plane, I'm VFR only and all it does is give false positives.
I did see a panel mounted apparatus that contained the alphabet and allowed you to select the current ATIS. Seemed useless to me.
I expect to hear about your LORAN and ADF.
The ATC radio/voice recorder is the most useless item in my plane.
If you miss a transmission, you're suppose to press a rewind button and it plays back the last 10 seconds or so.
The problem is, by the time you press the button (2 seconds) and listen to the radio call (10 more seconds) and assuming it comes back clear, you reach for the PTT button (another 2 seconds) ATC is usually recalling you on the radio again with an attitude. It's just better to ask them to "Say Again for N123A." and move on.
The E6B is another item (instrument) that once I purchased it and took my Knowledge test, it never left my flight bag...until I retired it to the junk room with my free-weights, treadmill and the dog's PediPaws sander.
The ash tray.
The little red bottle my wife bought me from Sporty's in case I have to relieve myself on a long x-country. Never used it and I'm convinced the gift was more of a joke than an "instrument" with utility.
Mutt Muffs. These are really cute and make for great pictures if you take one quick enough. Otherwise, the dog shakes them off in 4 seconds.
The Sporty's Sight-Level to determine if you're about to fly into a cloud...'nuff said.
Paper charts are the buggy-whips of this decade. They do make for great wallpaper in my office to push pins in to show where I've flown in my lifetime by GA. I use the WAC for this and they work great. I have the whole eastern 1/2 of country the wall to the foothills of the Rockies. I have white pins in the places I haven't flown, but have on the "bucket list".
I'm sure others will have some creative posts to this idea of "The Most unimportant/useless Aviation Items" we have or know of.
Gene