There is no AD associated with the wing prior to 2000-25-02 that I know of.
On my original wood wing spars there are only phenolic bushings, or sleeves as you call them, at the front spar butt end, 4 of them, and at each lift strut ends at the spars 3 each, front and rear. My new spars have aluminum bushings all at the same locations. There were never bushings at the rear spar butt end. I don't know of any other bushings in the spars.
I've owned my Champ since '85 and I've always been involved in it's maintenance, it's currently undergoing a full restoration.
Over the years there have been a number of problems and a few failures within the wing. Most of those are from hard aerobatics, damage like a wing strike on a hangar, or ground loop with the wing tip hitting the ground. Nails pulling out from the spars, cracked ribs are mostly from aerobatics, and compression cracks in the spars are from some kind of damage.
The original Champ was designed for a 65 HP engine with a VNE of 129mph. Over the years engines up 180 and 200 HP and the aerobatics that go with that have stressed the original spars much harder than anyone could have imagined in 1946.
I believe the Scout has had a few failures, what some people don't realize is the Scout is NOT approved for aerobatics, it's supposed to be a bush plane.
As for the OP questions, it's difficult to diagnose anything from 1000 miles away, and I'm no covering and paint expert. I would look closely at the logs to see if it's ever been covered since new. A lot of internal issues may need repairs after 42 years that you just can't fix without doing a recover. I would also find someone that knows Citabrias and is willing to help you inspect it, someone who doesn't have any investment in the plane, if you know what I mean. Not knowing anything about your friend, sometimes "friends" can turn out to be no friend at all. Do your research, find a second opinion and realize you may or may not be able to live with a plane with an ugly finish.