Clark1961
Touchdown! Greaser!
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Help me with this. My point was that the lighter fractions will still evaporate faster than the balance of the mix, leaving you with a mystery fuel. Not true? I figured Boyle's law pretty much assured that. But I'm not a petro guy, so I defer to expertise...
Hydrocarbons are sort of "interesting" solutions. The way we model the behavior is to characterize the effect or interaction of one molecular component on another molecular component. Methane in particular has a tremendous influence on heavier components. The effect can be to the point of some of the heavier components crystallizing if methane is allowed to escape (vaporize) from the mixture. Conversely, the presence of heavier ends can help lighter ends to remain in the mixture at a particular pressure and temperature.
We do a lot of testing to characterize the make-up of solutions. Once we have identified the components and the relative quantities present in a mixture we can sort of predict the mixture's physical properties. I say "sort of" because the predictions are typically poor unless we have data from observed physical behavior to tune our models.
So with all that said, will the mixture result in an unknown solution. To a degree, yes. Will the mixture actually change much? no, not under normal storage conditions. The avgas will reduce the vapor pressure and the losses from the mogas.