To be able to charge through the external port you need to do the following.
0. Avionics Bus 1 & 2 off (duh)
1. Master On (to energize the External Power Relay)
2. Pull Essential Bus Breakers (PFD, ADC, Nav 1, Comm 1) as there's no way to turn off the essential bus once the master is on
3. Turn off/down Standby Indicator Lights (instead of pulling the breaker)
4. Arm or keep off Standby Battery depending if you want it to charge* as well
* If you want the Standby battery to be charged as well you need to have it Armed when connected
I'm in the process of installing a Battery Minder lead for the Main Battery as I don't want to pull breakers after every flight to keep the battery maintained. Further, my power supply is not as good at maintaining the battery as the Battery Minder. I'm debating installing a Battery Minder lead for the Standby Battery as well, I'm just confirming in another thread if anyone has done this and where to connect it.