This type of frost is caused by radiative cooling. A clear sky allows the latent heat in the metal to radiate off into space and the surface drops below the dewpoint and frost forms. The light metals used in airplanes contributes to it, and aluminum transmits the heat faster than steel, too. It doesn't happen in the hangar because the roof prevents the radiation off into space, relecting it back to the metal.
We used to have it happen a lot when pulling the flight school airplanes out on a cool morning. The metal can actually fall below the ambient air temperature, forming the frost even though there's no fog. You would normally see fog if the air temp got below the dewpoint.
Unless you buy 99% industrial isopropyl, you'll end up with a mix of water and IPA. The alcohol evaporates, cooling the wing even further, and the water left behind freezes. Use the right stuff.
https://www.linkedin.com/pulse/frost-result-radiational-cooling-arjen-piest
Best reply yet. thanks for the info!