First off, I know very little about the chemistry of fuel. However, I work with several guys who came to my company directly from a nearby refinery, who represent nearly all levels of the refining operations, ie. operators, console techs (the guys who actually control the operations), supervisors, and a lab tech. At their refinery, they made basically 2 gasoline products, 87ish octane and 91-93ish octane pure gasoline. Anything other than pure gasoline gets added after the gas leaves the refinery, including the detergents and other things that fuel vendors put in their commercials to make their product stand out, including ethanol and the TEL in avgas. So it sounds like the Avgas companies just take 91-93ish octane pure gas and blend in some TEL, which boosts the octane rating up to 100. Wherever you fill up in your area, chances are it all came from the same refinery, then blended to certain specs.
I understand that it's been determined that lead is the devil, but what if the Avgas folks just added half or a quarter of the lead? If you cut the lead in half, wouldn't you have a 96-97 octane fuel? Or if you quartered it, wouldn't you have a 94-95 octane fuel? I'm not sure how much lead or octane is really needed for those high compression engines, but a fuel with a pretty high octane rating, that still retains some of the seemingly all important lead for lubrication and anti-knock, while reducing lead emissions by 50-75% seems like it would appease both sides, and would simply be a matter of dumping in less TEL on the back end of the refinery.
Then there are those of us who can run mogas. Personally, I use it almost all the time. There isn't a mogas pump at an airport anywhere near me, but I just fill up a 55 gal drum at the gas station and go pump it in the plane. It's not nearly as convenient as taxiing up to the pump, but it's worth it to me to do it this way. I understand than most people wouldn't go to the trouble to do it that way, but I do know a bunch of people what would use it if it were available on the field. So again, if lead is the debil, why the hell don't we have mogas pumps all over the place? That would significantly reduce lead emissions without having to really do anything, and it's easier to come by than any other fuel at nearly half the price of Avgas.