FAAO 8260.19H, paragraph 2-4-5 discusses the various monitoring categories and how they apply to establishing alternate minimums.
That's a behind-the-scenes determination, though, what a pilot cares about is what is in the Alternate Minimums section of the approach charts, if they are not standard.
For example, if an ILS is monitored in the tower, and the tower is not a 24-hour facility, the Alternate Minimums will read "NA when control tower closed".
Most VORs are monitored at the regional level at a centralized control center, so you usually won't see this kind of note on a VOR procedure. You will sometimes see it on an NDB procedure, but most often it will be on an ILS (or Loc-only)