That way you know the mags are cold before you go pushing around the plane by the prop with a warm engine
You no NOTHING of the sort. All you know is that the OFF switch temporarily worked when you switched through it. The cheap-ass key switches commonly used will often wear to the point where they can appear to be off and the key removed but they'll unground at least one of the mags. You could do all the hot mag checks on my old switch you wanted and it would still be hot half the time. The mechanic learned that the hard way when she was timing the mags and managed to discharge the cap through her hand.