What are your principal concerns? Li ion batteries have much higher energy densities that lead acid batteries. Depending on type, voltages per cell is 3-4 V. Cathode materials are mixed metal compounds with lithium and typically cobalt, iron, or manganese. The electrolyte for most Li ion batteries are liquid, organic, and flammable, which is a safety concern if batteries are physically damaged or experience high rates of discharge. Charging and discharging circuits must protect from overcharging or overdischarging to prevent irreversible damage. Self discharge rates can be high, much like NiMH batteries, although this problem has improved over time.
The Battery University web site is an excellent resource for understanding battery types. Probably more than you want to know.