If you can fit in the plane!
You can definitely fit two people in the pipistrel virus sw 912iS. I know, I flew in one with the owner. But the capacity for luggage (behind the front seats) is far from enormous, so pack light! I would not call the cockpit "roomy" for two people, but it is adequate. Far more than sufficient leg room, but width is a bit tight unless the pilot and passenger lean gently against the door windows, which is fine.
Unless you own a jet, no matter what you're flying, you'll definitely be ready to get out of the airplane, stretch your legs and walk around in wide open spaces for awhile when you finish a non-stop trip from California to Hawaii!
One potentially good feature of this airplane is... if you feel a bit claustrophobic after several hours, you can slow down for little awhile, open your door completely wide open (folds up against bottom of the high wing), and enjoy completely wide open spaces right next to you. I suppose there might be other reasons one might want to open the door for a little while too, but I won't discuss that here and now.
PS: If you don't buy the optional ballistic emergency parachute (designed to gently float the entire airplane to the ground (or ocean) in an emergency), that volume and mass is available for more baggage (but still not a generous volume).
The 300 liter extreme range tank option is expensive... about $20,000. With all the options one should have for flying missions like this, the total cost will probably fall between $175K and $190K USD... or even $200K if you go a bit crazy on options.